Lithium iodate (LiIO3)

Lithium iodate (LiIO3) crystal is a negative uniaxial crystal, with high nonlinear optical coefficient and wide transparency range, radiation damage resistance characteristics. It can be used for nonlinear acousto-optic and piezoelectric applications in a 347 nm ruby laser as a medium and narrow pulse, wide band ultrasonic transducer. It can also be used as two, three time frequency and mixing of medium and low power laser.

Product Description

Lithium iodate (LiIO3) crystal is a negative uniaxial crystal, with high nonlinear optical coefficient and wide transparency range, radiation damage resistance characteristics. It can be used for nonlinear acousto-optic and piezoelectric applications in a 347 nm ruby laser as a medium and narrow pulse, wide band ultrasonic transducer. It can also be used as two, three time frequency and mixing of medium and low power laser.

Main Features

High nonlinear optical coefficient, wide transparent range, wide phase matching range, good temperature stability of the refractive index, and low damage threshold value

Material Properties

Crystal structurehexagonal crystal system
Crystal structureaniaxial negative crystal
Point group6
Melting point420℃
Density4.487 g/cm3
Mohs hardness3.5–4.0
Transparent range280–4000nm
Absorption coefficient @1064 nm,<0.05cm-1
Refractive index @ 1,064 nmno= 1.8571, ne= 1.7165
@800 nmno= 1.8676, ne= 1.7245
@532 nmno= 1.8982, ne= 1.7480
Type 1 SHG Phase-matching range570–4000nm
Type 1 SHG Acceptance @1064 nm
Angle, and the mradcm0.77
Light spectrum,cm-1×cm12.74
Type 1 SHG Go @1064 nm, mrad74.3
Nonlinear coefficientd31=4.4 pm/V(@1064 nm)
Effective nonlinearitydeff = d31sinθ
Damage threshold>100MW/cm2@1064 nm, 10 ns
Sellmeier Equation (λ in μm)no2=3.415716+0.047031/(λ2-0.035306)-0.008801λ2
ne2=2.918692+0.035145/(λ2-0.028224)-0.003641λ2


Product Parameters

Dimensional tolerance±0.1mm
Optical aperture≧90%
Wavefront distortion≦λ/4 @ 633nm
Flatnessλ/4 @ 633nm
Finish20/10
Parallelism≦20"
Verticality≦5 ′
Angular deviation<±0.5°


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